Preheat the oven to 350°. Butter 9-inch round springform pan. Line bottom with a circle of parchment paper, then butter and flour the pan. Set aside. Sift flour, salt, baking soda, baking powder and cocoa powder in a bowl and set aside.
Place butter, chocolate and hot coffee in a large heatproof bowl and mix until chocolate is melted and smooth.
Stir in sugar and mix by hand until dissolved. Add buttermilk, vanilla and eggs and whisk until thoroughly combined and smooth.
Whisk the dry ingredients into the the chocolate mixture. The batter will be quite thin at this point.
Pour the batter evenly into prepared springform pan and bake for 1 hour, until a cake tester/toothpick comes out clean. Cool in the cake for 30 minutes, then turn remove from pan to a cooling rack and let cool completely. (The top will sink a little in the center and may slightly crack. This is OK.)
If your cake top is rounded, sunken or just not quite flat, use a serrated knofe and slice off a thin layer to flatten the top. Save the sliced off portion, crumble it up and sprinkle over the top of the cake for a yummy topping.